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Chemical Cycles

Author: Sophia

what's covered
In this lesson, you will learn about the carbon, nitrogen, and phosphorus cycles. Specifically, this lesson covers:

Table of Contents

1. What are Ecological or Biogeochemical Cycles?

The ecological or biogeochemical cycles, such as the various elements and water cycles, are the biogeochemical processes through which these elements and water are cycled through the ground, air, water and living organisms of the Earth. These are self-sustaining processes to recycle these vital and limited resources that are needed to sustain life on Earth.

These are sometimes called ecological cycles or biogeochemical cycles. Ecological cycles are the various self-regulating processes that recycle the Earth’s limited resources. Biogeochemical cycles are the biological, geological, and chemical processes that occur during each of these cycles.

These elements and water move between both nonliving (abiotic) and living (biotic) components of our ecosystem. Abiotics are non-living chemical and physical parts of the environment that affect living organisms and the functioning of the ecosystem. Biotics are living parts of the environment that affect living organisms and the functioning of the ecosystem. The ecosystem is the biological community of interacting organisms within their physical environment. These elements and water must be continually recycled for living organisms to survive. Each of these elements and water have a reservoir in nature.

terms to know
Ecological Cycle
The various self-regulating process that recycles the Earth’s limited resources.
Biogeochemical Cycle
The biological, geological, and chemical processes that occur during each of these cycles.
Abiotic
A non-living, chemical, and physical part of the environment that affects living organisms and the functioning of the ecosystem.
Biotic
A living part of the environment that affects living organisms and the functioning of the ecosystem.
Ecosystem
The biological community of interacting organisms within their physical environment.

2. The Carbon Cycle

We are carbon-based lifeforms. All living organisms are made of carbon and need carbon to survive. The carbon cycle is the way nature recycles carbon through our ecosystem.

EXAMPLE

Carbon is found naturally in our atmosphere in the form of carbon dioxide (COblank subscript 2). It is also found in the minerals and ores of the Earth’s crust and in the ocean and other water sources. Other reservoirs of carbon include all living organisms and decaying plant and animal materials, which we collectively call fossil fuels. Fossil fuels are fuels formed by the natural decaying process of dead organisms from long ago (hence the name fossil). Fossil fuels include oil, coal, natural gas, and peat.

In the aquatic portions of the Earth photosynthesis of plankton (tiny organisms that float in the water) and other vegetation takes carbon dioxide as a source of energy out of the water. However, respiration of aquatic animals and decomposition put carbon dioxide back into the water. Additionally, carbon compounds can be absorbed out of the water into the marine sediment or from the sediment into the water source. At the surface, oceans are a huge absorber of excess carbon dioxide from the atmosphere into the water, but at the same time, carbon dioxide is released into the atmosphere from the ocean. All of these processes occur as a steady state with almost equal amounts going into and out of the waterways. Steady state refers to chemical processes that are continually occurring in both directions but have relatively little net change over time.

did you know
In the air, carbon dioxide is absorbed by plants and released by animals, again in a steady-state process. However, humans are the biggest net producer of carbon dioxide into our atmosphere from the burning of fossil fuels in our cars and power plants. Over the past 80 years, our atmospheric carbon dioxide concentration has increased from 300 ppm to 400 ppm.

Shown is a schematic of a small portion of Earth with land and water shown. Arrows show the overall flow of carbon.  There is a fossil fuel deposit underneath the soil, carbon flows from that deposit to the surface. On the surface, vegetation both takes in and releases carbon. Power plants are shown releasing carbon. Crops both takes in and releases carbon. Cities release carbon into the atmosphere. Carbon flows from air to water. Water both releases and takes in carbon. Underneath the water, plankton shows a release and intake of carbon.  Finally, marine sediment, at the bottom of the ocean, both takes in and releases carbon.


terms to know
Fossil Fuel
Fuel formed by the natural decaying process of dead organisms from long ago (hence the name fossil). Fossil fuels include oil, coal, natural gas, and peat.
Steady State
The chemical process that’s continually occurring in both directions but has relatively little net change over time.

3. The Nitrogen Cycle

Nitrogen gas (Nblank subscript 2) is very unreactive because of the very strong triple bond between the nitrogen atoms. The general lack of reactivity of nitrogen allows for the remarkable ability of some bacteria to synthesize nitrogen compounds using atmospheric nitrogen gas as the source of one of the most exciting chemical events on our planet.

This process is one type of nitrogen fixation, which is the process where organisms convert atmospheric nitrogen into biologically useful chemicals. Nitrogen fixation also occurs when lightning passes through the air, causing molecular nitrogen to react with oxygen to form nitrogen oxides, which are then carried down to the soil. All living organisms require nitrogen compounds for survival. Unfortunately, most of these organisms cannot absorb nitrogen from their most abundant source—the atmosphere.

The nitrogen cycle is often referred to as nitrogen fixation, as seen in the figure below.

A flow chart is shown. A cow, grass, and a tree are shown in the center of the diagram. Downward-facing arrows lead from them to the phrase, “Decomposers ( aerobic and anaerobic bacteria and fungi ).” A downward-facing arrow leads to a space-filing model with one blue atom bonded to four white atoms. The model is labeled, “Ammonium ( N H subscript 4 ).” A right-facing arrow leads from this molecule to another molecule that is composed of a blue atom bonded to two red atoms. The model is labeled, “Nitrites ( N O subscript 2 superscript negative sign ).” Below this arrow is a picture of a circle with two rod-shaped structures. It is labeled, “Nitrifying bacteria.” Above the nitrites label is an upward-facing arrow leading to a blue atom single-bonded to three red atoms. The model is labeled, “Nitrates ( N O subscript 3 superscript negative sign ).” Next to this arrow is a picture of a circle with two rod-shaped structures labeled, “Nitrifying bacteria.” The nitrates label has a double-headed, upward-facing arrow that leads to two pictures: one of the roots of the tree which is labeled, “Assimilation,” and one leading to a picture of a circle with four oval-shaped structures labeled, “Denitrifying bacteria.” A left-facing arrow leads from this bacteria to a molecule made up of two atoms triple-bonded together and labeled, “Atmospheric nitrogen ( N subscript 2 ).” This molecule is connected to a downward-facing, double-headed arrow that leads to an image showing yellow filaments on a black background and a picture of a circle with four rod-shaped structures labeled, “Nitrogen-fixing soil bacteria.” An arrow leads from a picture of a plant’s roots to the yellow filaments and then to a photo of a circle with four oval-shaped structures labeled, “Nitrogen-fixing bacteria in root nodules.

EXAMPLE

To date, the only known kind of biological organisms capable of nitrogen fixation are microorganisms. These organisms employ enzymes called nitrogenases, which contain iron and molybdenum. Many of these microorganisms live in a symbiotic relationship with plants, with the best-known example being the presence of rhizobia in the root nodules of legumes, which are plants that produce their seeds in pods, such as peas and beans .

Large volumes of atmospheric nitrogen are necessary for making ammonia—the principal starting material used for preparation of large quantities of other nitrogen-containing compounds. Most other uses for elemental nitrogen depend on its inactivity. It is helpful when a chemical process requires an inert atmosphere.

EXAMPLE

Canned foods and luncheon meats cannot oxidize in a pure nitrogen atmosphere, so they retain a better flavor and color, and spoil less rapidly when sealed in nitrogen instead of air. This technology allows fresh produce to be available year-round, regardless of the growing season.

term to know
Nitrogen Fixation
The process where organisms convert atmospheric nitrogen into biologically useful chemicals.


4. The Phosphorus Cycle

Phosphorus is another important element whose cycle is important for life on Earth. Unlike the other cycles we have talked about so far (and the two remaining cycles), the atmosphere has virtually no role in the cycling of phosphorus. Most phosphorus compounds are solids, aqueous, or bound in living organisms. Most of the phosphorus cycle only uses the solid and water portions of the Earth.

EXAMPLE

Phosphorus is found in our soil and is very important to plant growth. Plants and vegetation take phosphorus out of the soil and fix it in their structures. Humans and animals eat that vegetation and use that as a source of phosphorus for their needs. Decomposition and other processes put that phosphorus back into the land. Many fertilizers and pesticides are rich in phosphorus and runoff from these absorb back into the soil and water supplies.

The biggest movement of phosphorus is from surface weathering which brings phosphorus-bearing rocks to the surface from within the Earth’s crust. Also physical erosion—the chemical and biological weathering of these rocks—bring phosphorus compounds into the water supply.

Shown is a schematic of a small portion of Earth with land and water shown. Arrows show the overall flow of phosphorus from the land to water and from the rocks to the surface of Earth. In addition, Soil phosphorus goes from the soil to plants. Then phosphorus goes from plants to animals and from animals to soil. Additionally, runoff from fertilizer goes into the soil and into the water. In the water, marine plants, marine animals, dissolved phosphates in water circulate phosphorus amongs themselves and eventually into the sediment.



5. The Oxygen Cycle

Oxygen is the most abundant element on the Earth and like carbon, nitrogen, and phosphorus is vital to life. All animals breathe oxygen and we cannot live without it. Oxygen plays a major part in all of these cycles. The main chemical in the carbon cycle is carbon dioxide. Nitrites (NO2-) and nitrates (NO3-) are important parts of the nitrogen cycle. Multiple oxygen compounds such as phosphates (PO43-), apatite (Ca5(PO4)₃OH), and other similar minerals and ores are important parts of the phosphorus cycle. Of course, oxygen is involved in the water cycle (oxygen is the O in H2O), as discussed in the next section.

Oxygen and carbon dioxide are exchanged constantly between all animals during respiration (oxygen in and carbon dioxide out as animals breathe). The reverse process occurs in photosynthesis in plants and vegetation (carbon dioxide in and oxygen out during photosynthesis). Another source of oxygen is water, which continually moves from the aquatic (water) to the terrestrial (land) to the atmosphere. This will be talked about in the last section of this lesson.

Water (H2O) falls as rain over land and over the sea, and animals and plants receive it. A part of the remaining water evaporates so that it condenses again to form clouds. Another part of the water falling on land either seeps into the interior of the Earth or flows through streams and rivers. Through photosynthesis, phytoplankton, plants, and trees incorporate CO2 and release O2 into the atmosphere. Through breathing, animals release CO2, while incorporating O2. Industries and volcanic eruptions also release CO2.


6. The Hydrological (or Water) Cycle

The carbon, nitrogen, phosphorus, and oxygen cycles were about recycling elements throughout our ecosystem. The last cycle we discuss will be about recycling the compound water throughout our ecosystem. Water is the most abundant compound on Earth. We find it in the water, land, and atmosphere. We also find it in all living organisms.

As you can see in the figure below, water moves from the aquatic (lakes, rivers, oceans, seas) portion of the Earth into the atmosphere through evaporation. The water then condenses into the clouds. Water in the form of rain, snow, or ice will fall from the clouds and accumulate in the terrestrial domain (land). From the land, the water will be absorbed into the soil or run off into the aquatic portion of the Earth. The cycle then starts all over.

summary
In this lesson, you learned about the ecological or biogeochemical cycles of the Earth, which is how vital and limited resources are recycled throughout our entire ecosystems. Next, you learned about the carbon, nitrogen, phosphorus, oxygen, and water cycles, which recycle these vital elements and compounds throughout our ecosystem.

Best of luck in your learning!

Source: THIS TUTORIAL HAS BEEN ADAPTED FROM OPENSTAX “CHEMISTRY: ATOMS FIRST 2E”. ACCESS FOR FREE AT Chemistry: Atoms First 2e. LICENSE: CREATIVE COMMONS ATTRIBUTION 4.0 INTERNATIONAL

Attributions
  • Global Carbon Cycle | Author: Silvania Avelar, Tessa S. van der Voort & Timothy I. Eglinton. Credit to Jack Cook, Woods Hole Oceanographic Institution, CC BY-SA 4.0 | License: Public Domain
  • Phosphorus Cycle | Author: Bonniemf Incorporates work by NASA Earth | License: Public Domain
  • Oxygen Cycle | Author: Eme Chicano | License: Public Domain
  • Water Cycle | Author: Ehud Tal | License: Public Domain
Terms to Know
Abiotic

A non-living, chemical, and physical part of the environment that affects living organisms and the functioning of the ecosystem.

Biogeochemical Cycle

The biological, geological, and chemical processes that occur during each of these cycles.

Biotic

A living part of the environment that affects living organisms and the functioning of the ecosystem.

Ecological Cycle

The various self-regulating process that recycles the Earth’s limited resources.

Ecosystem

The biological community of interacting organisms within their physical environment.

Fossil Fuel

Fuel formed by the natural decaying process of dead organisms from long ago (hence the name fossil). Fossil fuels include oil, coal, natural gas, and peat.

Nitrogen Fixation

The process where organisms convert atmospheric nitrogen into biologically useful chemicals.

Steady State

The chemical process that’s continually occurring in both directions but has relatively little net change over time.